Chakraborty, Uttam and Muehldorf, Bernd and van Velzen, Niels J. C. and de Bruin, Bas and Harder, Sjoerd and Wolf, Robert (2016) [(CpNi)-Ni-Ar{Ga(nacnac)}]: An Open-Shell Nickel(I) Complex Supported by a Gallium(I) Carbenoid (Cp-Ar = C-5(C6H4-4-Et)(5), nacnac = HC[C(Me)N-(C6H3)-2,6-iPr(2)](2)). INORGANIC CHEMISTRY, 55 (6). pp. 3075-3078. ISSN 0020-1669, 1520-510X
Full text not available from this repository. (Request a copy)Abstract
The 17 valence electron (VE) open-shell nickel gallanediyl complex [(CpNi)-Ni-Ar{Ga(nacnac)}] (3, Ar = C-5(C6H4-4-Et)(5), nacnac = HC[C(Me)-N(C6H3-2,6-iPr(2))](2)), having an unsupported Ni-Ga bond, was synthesized from [(CpNi)-Ni-Ar(mu-Br)](2) (1) by reducing the adduct [(CpNi)-Ni-Ar(mu-Br){Ga(nacnac)}] (2) or, alternatively, trapping the "(CpNiI)-Ni-Ar" synthon with Ga(nacnac); spectroscopic and DFT studies showed that the single unpaired electron in 3 resides mainly at the Ni center.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | BISIMIDINATE GA(DDP); OLEFIN COMPLEXES; BASIS-SETS; GA BONDS; CL BOND; INSERTION; ACTIVATION; CHEMISTRY; LIGANDS; COORDINATION; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Robert Wolf |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 26 Mar 2019 09:31 |
| Last Modified: | 26 Mar 2019 09:31 |
| URI: | https://pred.uni-regensburg.de/id/eprint/3234 |
Actions (login required)
 |
View Item |
