Kubicki, Marek M. and Schwarz, Patrick and Meier, Walter and Wachter, Joachim and Zabel, Manfred (2007) [{(C5Me5)(2)Nb}(2)PdTe4], a heterometallic palladium telluride cluster with a planar PdTe4 fragment. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 692 (18). pp. 3931-3935. ISSN 0022-328X,
Full text not available from this repository. (Request a copy)Abstract
The reaction of [Cp-2*Nb(Te2H)] (Cp* = eta(5)-C5Me5) with [Pd(DBA)(2)] (DBA = dibenzylidenacetone) and dppm (bis(diphenylphosphanyl)methane) gave the new tetratelluropalladate cluster [(Cp-2*Nb)(2)PdTe4] (1), which has been characterised by means of elemental analysis, FD-MS and X-ray crystallography. The structure of compound I contains a planar PdTe4 rectangle to which two niobocene groups are coordinated. DFT calculations on the hypothetical [PdTe4](2-) anion and comparison of the results with those of the W and Ni homologues show that the planar arrangement of Te ligands in 1 is due to the intrinsic property of the central Pd atom. (c) 2007 Elsevier B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | METAL; TRANSITION; MOLECULES; niobium; palladium; tellurium; cluster chemistry; structure |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Arbeitskreis Dr. Joachim Wachter |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 01 Dec 2020 14:09 |
| Last Modified: | 01 Dec 2020 14:09 |
| URI: | https://pred.uni-regensburg.de/id/eprint/32388 |
Actions (login required)
 |
View Item |
