Kunkely, Horst and Vogler, Arnd (2007) Excited state properties of silver(I) nitrite complexes: Nitrogen conproportionation in Ag(NH3)NO2 induced by LLCT excitation. INORGANIC CHEMISTRY COMMUNICATIONS, 10 (7). pp. 784-786. ISSN 1387-7003,
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The complex Ag(NH3)NO2, which can be viewed as a ligand-based mixed-valence compound, undergoes a photoconproportionation of nitrogen from -III and +III to 0. It is suggested that this photolysis originates from a NH3 to NO2- LLCT state which is populated from a NO2- IL state. In this context, the excited state properties of AgNO2 and Ag(H2O)NO2 are also discussed. (c) 2007 Elsevier B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | SALTS; NO2; AG; electronic spectra; LLCT; nitrite complexes; silver complexes; photochemistry |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 02 Dec 2020 11:54 |
| Last Modified: | 02 Dec 2020 11:54 |
| URI: | https://pred.uni-regensburg.de/id/eprint/32544 |
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