Roznyatovskaya, Nataliya V. and Laurinavichute, Veronika K. and Tsirlina, Galina A. and Mirsky, Vladimir M. (2007) Electrochemistry and catalytic behavior of immobilized binuclear complexes of copper(II) and nickel(II) with Robson type ligand. JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 11 (7). pp. 981-992. ISSN 1432-8488, 1433-0768
Full text not available from this repository. (Request a copy)Abstract
Various systems containing immobilized binuclear copper(II) and nickel(II) complexes with Robson type ligand ([M2L]Cl-2) are studied and compared in relation to catalysis of hydrogen peroxide reduction. Molecular complexes adsorbed on mercury and gold, crystalline complexes immobilized in the carbon paste electrode, and complex species entrapped into polyphenol-modified gold electrodes are considered. Electrocatalysis is assumed to result from the formation of H2O2-[M2L]Cl-2 adduct, not from mediating redox transformations. Possible geometry of the formed reaction layers supporting adduct formation is discussed.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | HYDROGEN-PEROXIDE; REDUCTION; SURFACE; ELECTROCATALYSIS; PHTHALOCYANINES; ELECTRODE; DIOXYGEN; binuclear copper macrocyclic complex; cyclic voltammetry; adsorption; carbon paste electrodes; electroreduction |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Analytische Chemie, Chemo- und Biosensorik > Chemo- und Biosensorik (Prof. Antje J. Bäumner, formerly Prof. Wolfbeis) |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 02 Dec 2020 12:18 |
| Last Modified: | 02 Dec 2020 12:18 |
| URI: | https://pred.uni-regensburg.de/id/eprint/32563 |
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