Luo, Qunli and Eibauer, Stefan and Reiser, Oliver (2007) Novel bis(oxazole) pincer ligands for catalysis: Application in Suzuki-Miyaura cross coupling reactions under aerobic conditions. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 268 (1-2). pp. 65-69. ISSN 1381-1169,
Full text not available from this repository. (Request a copy)Abstract
Introducing bis(oxazole) ligands to catalysis: novel bis(oxazole) ligands could be readily synthesized from isophthaloyl dichlorides and ethyl glycinate hydrochlorides or 6-aminoacetophenone hydrochloride. Their corresponding pincer palladium complexes proved to be extremely robust catalysts for Suzuki-Miyaura cross coupling reactions, allowing the synthesis of biaryls under aerobic conditions with turn over numbers of up to 790,000 and turn over frequencies of up to 49,000h(-1). (c) 2007 Elsevier B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ASYMMETRIC CATALYSIS; ARYLBORONIC ACIDS; BENZYLIC HALIDES; ARYL BROMIDES; COMPLEXES; CYCLOPROPANATION; bis(oxazoles); pincer ligands; Suzuki-Miyaura cross coupling; palladium; biaryls |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 04 Dec 2020 12:26 |
| Last Modified: | 04 Dec 2020 12:26 |
| URI: | https://pred.uni-regensburg.de/id/eprint/32836 |
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