Luminescent dual sensor for time-resolved imaging of pCO(2) and pO(2) in aquatic systems

Schroeder, Claudia R. and Neurauter, Gerhard and Klimant, Ingo (2007) Luminescent dual sensor for time-resolved imaging of pCO(2) and pO(2) in aquatic systems. MICROCHIMICA ACTA, 158 (3-4). pp. 205-218. ISSN 0026-3672,

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Abstract

An optical dual sensor for the two-dimensional detection of pCO(2) and pO(2) is described. Tris(tetraoctylammonium)-8-hydroxypyrene-1,3,6-trisulfonate ((TOA)(3)HPTS) acting together with the lipophilic buffer tetraoctylammonium hydrogen carbonate ((TOA)HCO3) as pCO(2)-sensing system along with the oxygen indicator tris(4,7-diphenyl-1,10-phenanthroline) ruthenium(II) bis(3-(trimethylsilyl)-1-propanesulfonate) (Ru(dpp)(3)TMS2) are incorporated into a single layer ethyl cellulose matrix. A second layer of black silicone rubber served as an optical isolation. The two indicators were simultaneously excited with a 460-nm LED, and a fast-gateable CCD camera was used as the detector. The time-gated imaging scheme enables the mapping of pCO(2) and pO(2) within one measurement, where images in three different time windows during and after a series of square-shaped excitation pulses are recorded. A numerical evaluation method for the resolution of the single parameter maps from these three overall images is described. The response of the sensor has been optimized for use in aquatic systems.

Item Type: Article
Uncontrolled Keywords: PRESSURE-SENSITIVE PAINT; FIBER-OPTIC SENSOR; CARBON-DIOXIDE; OXYGEN SENSORS; PLANAR OPTODES; WIND TUNNELS; PH; FLUORESCENCE; FLUOROSENSOR; TEMPERATURE; optical dual sensor; planar dual optode; simultaneous pCO(2) and pO(2) imaging; carbon dioxide and oxygen mapping
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Analytische Chemie, Chemo- und Biosensorik > Chemo- und Biosensorik (Prof. Antje J. Bäumner, formerly Prof. Wolfbeis)
Depositing User: Dr. Gernot Deinzer
Date Deposited: 14 Dec 2020 07:27
Last Modified: 14 Dec 2020 07:27
URI: https://pred.uni-regensburg.de/id/eprint/32842

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