Zabel, Manfred and Pavlovskii, V. I. and Poznyak, A. L. (2007) Crystal structure of barium (cyclohexane-1,2-diaminetetraacetato)cobaltate(III) nonahydrate Ba[Co(Cdta)](2) center dot 9H(2)O. RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 52 (4). pp. 551-555. ISSN 0036-0236, 1531-8613
Full text not available from this repository.Abstract
The crystal structure of Ba[Co(Cdta)](2) center dot 9H(2)O has been determined by X-ray diffraction. The crystals are monoclinic, a = 15.9415(10) angstrom, b = 7.8449(6) angstrom, c = 32.230(2) angstrom, beta = 100.387(8)degrees, Z = 4, space group C2/c)). The cyclohexane-1,2-diaminetetraacetate ion forms the octahedral [Co(Cdta)](-) complex through two donor nitrogen atoms and four oxygen atoms and is also connected to two barium atoms through oxygens. The Ba atoms are on a twofold axis. Its nearest environment comprises five O atoms of water molecules, one also being located on a twofold axis, and four O atoms of the four neighboring complex ions. This gives infinite layers parallel to the ab plane. All water molecules form hydrogen bonds within one layer.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 21 Dec 2020 09:53 |
| Last Modified: | 21 Dec 2020 09:53 |
| URI: | https://pred.uni-regensburg.de/id/eprint/33011 |
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