Zabel, Manfred and Pavlovskii, V. I. and Poznyak, A. L. (2007) Crystal structure of barium trans(O)-cis(CN)-Bis(2-picolinato)dicyanocobaltate(III) hydrate [Ba(H2O)(4)][Co(Pic)(2)(CN)(2)](2) center dot 4.41H(2)O. RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 52 (3). pp. 367-370. ISSN 0036-0236, 1531-8613
Full text not available from this repository.Abstract
In the crystals of [Ba(H2O)(4)][Co(Pic)(2)(CN)(2)](2) center dot 4.41H(2)O (tetragonal system, a = b = 10.9390(4) angstrom, c = 31.7624(15) angstrom, Z = 4, space group P4(3)), the trans(O)-cis(CN)-[Co(Pic)(2)(CN)(2)](-) anions are incorporated into cellular infinite layers whose sites contain Ba2+ ions, which are connected to four neighboring complexes through the oxygen atoms of the carboxy groups of the 2-picolinate ions. Four O atoms of the water molecules complete the Ba coordination polyhedron to a distorted square antiprism.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 22 Dec 2020 07:24 |
| Last Modified: | 22 Dec 2020 07:24 |
| URI: | https://pred.uni-regensburg.de/id/eprint/33157 |
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