Kunkely, Horst and Vogler, Arnd (2007) Luminescence of the oxonium ions O(ML)(+)(3) with ML = (AuPPh3)-P-I and (HgCl)-Cl-II. INORGANIC CHEMISTRY COMMUNICATIONS, 10 (2). pp. 148-150. ISSN 1387-7003,
Full text not available from this repository. (Request a copy)Abstract
The oxonium ions O((AuPPh3)-P-1)(3)(+) and O((HgCl)-Cl-II)(3)(+) are phosphorescent at r.t. and 77 K, respectively. It is suggested that these ions which are characterized by a rather flat trigonal pyramid in the ground state undergo a distortion to a steeper pyramid in their phosphorescent states. This structural change is caused by metal-metal bonding in the excited state. (c) 2006 Elsevier B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | GOLD(I) COMPLEXES; PHOTOLUMINESCENCE; electronic spectra; photoluminescence; phosphorescence; gold; mercury; oxonium |
| Subjects: | 600 Technology > 610 Medical sciences Medicine |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 22 Dec 2020 12:14 |
| Last Modified: | 22 Dec 2020 12:14 |
| URI: | https://pred.uni-regensburg.de/id/eprint/33232 |
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