Wang, Su-Na and Bai, Junfeng and Li, Yi-Zhi and Scheer, Manfred and You, Xiao-Zeng (2007) Metal disordering Cu(II) supramolecular polymers constructed from a tripodal ligand possessing two different functional groups. CRYSTENGCOMM, 9 (3). pp. 228-235. ISSN 1466-8033,
Full text not available from this repository. (Request a copy)Abstract
Two novel coordination polymers with double-layer structures were constructed from a tripodal ligand TCMB (1,3,5-tris(carboxymethoxy) benzene) by controlling the solvent and diffusion velocity of the reaction systems. Both solvated isomers [Cu-3(TCMB)(2)(C5H5N)(3)(H2O)(3) center dot 10H(2)O] (1, P6/m, a = b = 16.753( 1), c = 10.811( 1) angstrom, alpha = beta = 90.00 degrees, gamma = 120.00 degrees) and [Cu-3(TCMB)(2)(C5H5N)(3)(H2O)(3) center dot 7.66H(2)O center dot DMF] (2. P-3, a = b = 28.937( 3), c = 10.694( 1) angstrom, alpha = beta = 90.00 degrees, gamma = 120.00 degrees) exhibit peculiar metal disordering with fixed ligands due to the fact that the ligand can provide excessive potential coordinative sites with deficient metal centers available. Supramolecular isomerism induced by metal disordering was found for the first time.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | COORDINATION POLYMERS; ORGANIC FRAMEWORKS; ADSORPTION PROPERTIES; COPPER(II) COMPLEX; BUILDING-BLOCKS; RATIONAL DESIGN; DOUBLE-LAYER; SINGLE; MOLECULES; ISOMERISM; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 11 Jan 2021 14:13 |
| Last Modified: | 11 Jan 2021 14:13 |
| URI: | https://pred.uni-regensburg.de/id/eprint/33386 |
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