Brau, Michael F. and Pfitzner, Arno (2007) (HgBr2)(3)(AS(4)S(4))(2): An adduct of HgBr2 molecules and undistorted AS(4)S(4) cages. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 633 (7). pp. 935-937. ISSN 0044-2313,
Full text not available from this repository. (Request a copy)Abstract
(HgBr2)(3)(AS(4)S(4))(2) is obtained by high temperature reaction of stoichiometric amounts of HgBr2 and AS4S4. It crystallizes in the monoclinic space group P2(1)/c with the lattice constants a = 9.593(5) angstrom, b = 11.395(5) angstrom, c = 13.402(5) angstrom, beta = 107.27(3)degrees, V = 1399(1) angstrom(3), and Z = 2. The crystal structure consists of molecular units built from two undistorted AS(4)S(4) cages which are coordinated weakly by three almost linear HgBr2 units. Raman spectra clearly indicate minor bonding interactions between HgBr2 and AS(4)S(4).
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | CRYSTAL-STRUCTURE; COPPER IODIDE; SPECTROSCOPIC CHARACTERIZATION; MERCURY; HALIDES; (CUI)(3)P4SE4; POLYMER; FAMILY; SCREWS; CHAINS; mercury halides; molecular adducts; arsenic sulfides; crystal structures; Raman spectroscopy |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Arno Pfitzner |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 15 Jan 2021 06:29 |
| Last Modified: | 15 Jan 2021 06:29 |
| URI: | https://pred.uni-regensburg.de/id/eprint/33630 |
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