Gheorghe, Alexandru and Cuevas-Yanez, Erick and Horn, Joachim and Bannwarth, Willi and Narsaiah, Banda and Reiser, Oliver (2006) A facile strategy to a new fluorous-tagged, immobilized TEMPO catalyst using a click reaction, and its catalytic activity. SYNLETT (17). pp. 2767-2770. ISSN 0936-5214,
Full text not available from this repository. (Request a copy)Abstract
A new fluorous-tagged TEMPO catalyst was prepared by a facile approach using the copper-catalyzed azide-alkyne cycloaddition as the ligation method. A fluorous F-17-CLICK-TEMPO showed excellent activity and selectivity in the oxidation of alcohols to aldehydes using bleach as the terminal oxidant. Moreover, the catalyst could be easily recovered using silica gel 60 and recycled in four cycles without loss of activity.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | POLY(ETHYLENE GLYCOL)-SUPPORTED TEMPO; SELECTIVE OXIDATION; PERFLUORINATED SOLVENTS; HUISGEN CYCLOADDITION; PARALLEL SYNTHESIS; AEROBIC OXIDATION; METAL-FREE; ALCOHOLS; CHEMISTRY; EFFICIENT; catalyst immobilization; fluorous; oxidation; click chemistry; TEMPO |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 20 Jan 2021 09:38 |
| Last Modified: | 20 Jan 2021 09:38 |
| URI: | https://pred.uni-regensburg.de/id/eprint/33871 |
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