Modular synthesis of chiral pentadentate bis(oxazoline) ligands

Seitz, Michael and Kaiser, Anja and Tereshchenko, Alexander and Geiger, Christian and Uematsu, Yukitaka and Reiser, Oliver (2006) Modular synthesis of chiral pentadentate bis(oxazoline) ligands. TETRAHEDRON, 62 (42). pp. 9973-9980. ISSN 0040-4020,

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Abstract

Highly modular N,Y,Z,Y,N-ligands (Y=N, O, S; Z=N, NO, OH, OMe) have been prepared using bis(oxazoline) building blocks either as nucleophiles or as electrophiles in coupling reactions with central aromatic units. This way, a great variety of pentadentate bis(oxazoline) ligands in diastereo- and enantiomerically pure form become readily available, which are useful for the construction of helical metal complexes with predetermined chirality. (c) 2006 Elsevier Ltd. All rights reserved.

Item Type: Article
Uncontrolled Keywords: JM-PHOS LIGANDS; ASYMMETRIC CATALYSIS; OXAZOLINE LIGANDS; COPPER(II) COMPLEXES; ALLYLIC ALKYLATIONS; HELICAL CHIRALITY; CRYSTAL-STRUCTURE; HYDROGENATION; KETONES; DESIGN;
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser
Depositing User: Dr. Gernot Deinzer
Date Deposited: 20 Jan 2021 09:45
Last Modified: 20 Jan 2021 09:45
URI: https://pred.uni-regensburg.de/id/eprint/33874

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