Kunkely, Horst and Vogler, Arnd (2006) Can silver exert a heavy-atom effect in organic ligands? Intraligand phosphorescence of Ag(binap)NO3 with binap=2,2 '-bis (diphenylphosphino)-1,1 '-binaphthyl under ambient conditions. INORGANIC CHEMISTRY COMMUNICATIONS, 9 (8). pp. 866-868. ISSN 1387-7003,
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The solid compound Ag(binap)NO3 with binap = 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl shows an IL phosphorescence at lambda(max) = 510 nm under ambient conditions. The silver-phosphine bonding is sufficiently covalent to transmit the heavy-atom effect of silver to the binaphthyl chromophore. (C) 2006 Elsevier B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | CHARGE-TRANSFER STATE; OPTICAL-PROPERTIES; CRYSTAL-STRUCTURES; EXCITED-STATES; COMPLEXES; METAL; LUMINESCENCE; PHOTOPHYSICS; MONONUCLEAR; ABSORPTION; electronic spectra; intraligand excited states; phosphorescence; silver complexes; phosphine complexes; heavy-atom effect |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 09 Feb 2021 06:26 |
| Last Modified: | 09 Feb 2021 06:26 |
| URI: | https://pred.uni-regensburg.de/id/eprint/34227 |
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