Braeu, Michael F. and Pfitzner, Arno (2006) [Cu(CN)en(2)]I-copper amine propellers. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 61 (7). pp. 775-778. ISSN 0932-0776,
Full text not available from this repository. (Request a copy)Abstract
Light blue [Cu(CN)en(2)]I was prepared by reaction of copper iodide with ethylenediamine (en) and potassium cyanide in acetonitrile in air. It crystallizes in the space group C2 (No. 5) with a = 11.082(6), b = 7.155(2), c = 9.017(3) angstrom, beta = 127.00(3)degrees, and Z = 2. The structure was refined from 1069 unique reflections and 90 parameters. The refinement converged to R1 = 0.018 and wR2 = 0.041 (all reflections). Copper has a trigonal bi-pyramidal environment formed by two en molecules and one CN- anion. The iodine anion shows no direct contact to the Cu2+ center. The propeller shaped complexes [Cu(CN)en(2)](+) are all oriented parallel in the crystal structure. [Cu(CN)en(2)](+) cations and I- anions form a zincblende related arrangement.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | CRYSTAL-STRUCTURE; REFINEMENT; HALIDES; copper (II) complexes; amines; cyanide |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Arno Pfitzner |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 11 Feb 2021 10:46 |
| Last Modified: | 11 Feb 2021 10:47 |
| URI: | https://pred.uni-regensburg.de/id/eprint/34421 |
Actions (login required)
 |
View Item |
