Phase transition in dichloro(ethylenediamine)copper(II) crystals [(En)CuCl(mu(3)-Cl)] and their structure

Zabel, Manfred and Pawlowski, V. I. and Poznyak, A. L. (2006) Phase transition in dichloro(ethylenediamine)copper(II) crystals [(En)CuCl(mu(3)-Cl)] and their structure. JOURNAL OF STRUCTURAL CHEMISTRY, 47 (3). pp. 585-588. ISSN 0022-4766, 1573-8779

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Abstract

Dichloro(ethylenediamone)copper(II) crystals undergo a phase transition at 138 K. X-ray crystal structure analysis at 123 K and 173 K showed that the phase transition is associated with ordering of both carbon atoms; space group changes from P2(1)/m to P2(1)/c, and the c parameter of the unit cell is nearly doubled.

Item Type: Article
Uncontrolled Keywords: ; copper(II) complexes; crystal structure; phase transition
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Anorganische Chemie
Depositing User: Dr. Gernot Deinzer
Date Deposited: 15 Feb 2021 13:02
Last Modified: 15 Feb 2021 13:02
URI: https://pred.uni-regensburg.de/id/eprint/34593

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