Kunkely, Horst and Vogler, Arnd (2006) Photolysis of tetraphenylcyclobutadiene palladium chloride induced by LMCT excitation. INORGANIC CHEMISTRY COMMUNICATIONS, 9 (2). pp. 248-250. ISSN 1387-7003, 1879-0259
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The complex tetraphenylcyclobutadiene palladium(IV) chloride shows a longest-wavelength absorption lambda(max) = 530 nm which is assigned to a LMCT transition from the C4Ph4 dianion to Pd(IV). LMCT excitation leads to the release of Pd(CH3CN)(2)Cl-2 and neutral C4Ph4 which dimerizes to octaphenylcyclooctatetraene. (c) 2005 Elsevier B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | METAL COMPLEXES; electronic spectra; LMCT; palladium; cyclobutadiene complexes; photochemistry |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 24 Feb 2021 07:56 |
| Last Modified: | 24 Feb 2021 07:56 |
| URI: | https://pred.uni-regensburg.de/id/eprint/34990 |
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