Synthesis of polymer bound azabis(oxazoline) ligands and their application in asymmetric cyclopropanations

Werner, Heiko and Herrerias, Clara I. and Glos, Michael and Gissibl, Anja and Fraile, Jose M. and Perez, Ignacio and Mayoral, Jose A. and Reiser, Oliver (2006) Synthesis of polymer bound azabis(oxazoline) ligands and their application in asymmetric cyclopropanations. ADVANCED SYNTHESIS & CATALYSIS, 348 (1-2). pp. 125-132. ISSN 1615-4150, 1615-4169

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Abstract

Aza(bisoxazoline) ligands were attached to various polymeric supports and the resulting immobilized ligands were evaluated in copper(I)-catalyzed asymmetric cyclopropanations. The efficiency of these transformations depends greatly on the polymeric support, on the protocol being applied for the immobilization of the ligands, and on the preparation of the catalysts.

Item Type: Article
Uncontrolled Keywords: ENANTIOSELECTIVE CATALYSIS; MACROPOROUS POLYMERS; COPPER-COMPLEXES; CHIRAL LIGANDS; BIS(OXAZOLINE); PHASE; EFFICIENT; SUPPORT; OLEFINS; asymmetric cyclopropanation; azabis(oxazolines); copper; immobilization; N ligand; polymer-supported catalyst
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser
Depositing User: Dr. Gernot Deinzer
Date Deposited: 01 Mar 2021 06:04
Last Modified: 01 Mar 2021 06:04
URI: https://pred.uni-regensburg.de/id/eprint/35042

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