Jiang, Guoqing and Li, Yizhi and Hua, Weijie and Song, You and Bai, Junfeng and Li, Shuhua and Scheer, Manfred and You, Xiaozeng (2006) A supramolecular assembly of {Fe10} molecular wheels with tubular structures. CRYSTENGCOMM, 8 (5). pp. 384-387. ISSN 1466-8033,
Full text not available from this repository. (Request a copy)Abstract
A 3-D supramolecular assembly of {Fe-10} molecular wheels, [Fe(CH3O)(2)(O2CCH2O - Ph)](10) center dot 6H(2)O ( 1) with tubular structure was successfully prepared by a novel approach of simple modification of the building blocks for making symmetric clusters, Fe-10. The diameter of the tubes is approximately 8.9 angstrom. Meanwhile, this tubular structure as the host traps hexameric clusters of water and the magnetic property of complex 1 shows that antiferromagnetic interactions exist between the high - spin iron(III) ions ( S = 5/2) with J = 5.36 cm(-1) and g = 2.03.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | FERRIC WHEELS; COMPLEXES; DESIGN; IRON; FRAMEWORKS; POLYMERS; STATE; UNIT; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 01 Mar 2021 11:08 |
| Last Modified: | 01 Mar 2021 11:08 |
| URI: | https://pred.uni-regensburg.de/id/eprint/35112 |
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