Optical properties of Ag(tripod)X with tripod=1,1,1-tris(diphenylphosphinomethyl)ethane and X- = Cl- and I-: Intraligand and ligand-to-ligand charge transfer

Kunkely, Horst and Vogler, Arnd (2006) Optical properties of Ag(tripod)X with tripod=1,1,1-tris(diphenylphosphinomethyl)ethane and X- = Cl- and I-: Intraligand and ligand-to-ligand charge transfer. INORGANICA CHIMICA ACTA, 359 (1). pp. 388-390. ISSN 0020-1693, 1873-3255

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Abstract

The complexes Ag-I(tripod)X with tripod = 1,1,1-tris(diphenylphosphinomethyl)ethane and X- = Cl- and I- are luminescent in solution at r.t. It is suggested that the emission is a phosphorescence which originates from a tripod intraligand state for X = Cl (lambda(max) = 464 nm) and a X- -> tripod ligand-to-ligand charge transfer state for X = I (lambda(max) = 482 nm). (c) 2005 Elsevier B.V. All rights reserved.

Item Type: Article
Uncontrolled Keywords: METAL-COMPLEXES; TRANSFER STATE; LUMINESCENCE; PHOTOLUMINESCENCE; TRANSITION; electronic spectra; luminescence; charge transfer; silver; phosphine complexes
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler
Depositing User: Dr. Gernot Deinzer
Date Deposited: 02 Mar 2021 08:07
Last Modified: 02 Mar 2021 08:07
URI: https://pred.uni-regensburg.de/id/eprint/35175

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