Kunkely, Horst and Vogler, Arnd (2005) Photochemistry of trichloro(phenylazo)bis(triphenylphosphine)ruthenium(II) induced by Ru to phenyldiazonium MLCT excitation. INORGANIC CHEMISTRY COMMUNICATIONS, 8 (12). pp. 1185-1186. ISSN 1387-7003, 1879-0259
Full text not available from this repository. (Request a copy)Abstract
The complex trichloro(phenylazo)bis(triphenylphosphine)ruthenium(II) shows a longest-wavelength absorption at lambda(max) = 520 nm which is assigned to a Ru(II) -> phenyldiazonium(+) MLCT transition. MLCT excitation leads to the oxidation of the metal and reduction of the diazonium cation which decays to nitrogen and phenyl radical. (c) 2005 Elsevier B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | NITROSYL COMPLEXES; RUTHENIUM; LIGAND; STATES; SALTS; electronic spectra; MLCT; photochemistry; ruthenium; phenyldiazonium |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 14 Apr 2021 08:55 |
| Last Modified: | 14 Apr 2021 08:55 |
| URI: | https://pred.uni-regensburg.de/id/eprint/35359 |
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