Pfitzner, Arno and Zabel, Manfred and Rau, Franz (2005) Preparation and crystal structure of MnBiS2Br. MONATSHEFTE FUR CHEMIE, 136 (12). pp. 1977-1983. ISSN 0026-9247,
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Black single crystals of MnBiS2Br were obtained by the reaction of stoichiometric amounts of alpha-MnS, Bi, S, and BiBr3 (3:2:3:1) at 600 degrees C for 4 weeks. The compound crystallises in the monoclinic system, space group C2/m, with a = 12.767(2), b = 3.9468(4), c = 9.574(1) A, beta = 90.87(2)degrees, and Z = 4. The crystal structure refinement based on 720 reflections converged at R = 0.0244 and wR2 = 0.0579, respectively. MnBiS2Br forms a layer structure consisting of MnS6 octahedra, MnS2Br4 octahedra, and BiS3+2 pyramids.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ; manganese; bismuth; sulphur; bromine; sulfosalts; crystal structure |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Arno Pfitzner |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 20 Apr 2021 11:25 |
| Last Modified: | 20 Apr 2021 11:25 |
| URI: | https://pred.uni-regensburg.de/id/eprint/35383 |
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