Lin, Zhihong and Wu, Meng and Wolfbeis, Otto S. (2005) Time-resolved fluorescent chirality sensing and imaging of malate in aqueous solution. CHIRALITY, 17 (8). pp. 464-469. ISSN 0899-0042, 1520-636X
Full text not available from this repository. (Request a copy)Abstract
Chiral discrimination of malates in aqueous solutions at near-neutral pH is achieved through fluorescence measurement and imaging using the europium-tetracycline complex (EuTc) as a fluorescent probe. The method is based on the significantly different fluorescence properties of the ternary complexes (Eu-Tc-malate) formed between EuTc and the enantiomeric malates. The enantiomeric excess (ee) of chiral malates can be quantified by both steady-state and time-resolved fluorescence, using either a conventional fluorescence microplate reader or fluorescence imaging. It offers a facile and sensitive method for high-throughput chiral discrimination. (C) 2005 Wiley-Liss, Inc.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | LANTHANIDE COMPLEXES; ENANTIOMERIC EXCESS; COORDINATION CHEMISTRY; MOLECULAR RECOGNITION; HYDROGEN-PEROXIDE; MALIC-ACID; LUMINESCENCE; LIGAND; SENSOR; DISCRIMINATION; enantiomeric discrimination; time-resolved fluorescence; europium chiral sensing; imaging; malate |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Analytische Chemie, Chemo- und Biosensorik > Chemo- und Biosensorik (Prof. Antje J. Bäumner, formerly Prof. Wolfbeis) |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 26 Apr 2021 07:48 |
| Last Modified: | 26 Apr 2021 07:48 |
| URI: | https://pred.uni-regensburg.de/id/eprint/35549 |
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