Pawlowski, Valeri and Knoer, Guenther and Lennartz, Christian and Vogler, Arnd (2005) Luminescence and theoretical studies of Cu(tripod)X [tripod=1,1,1-tris-(diphenylphosphanylmethyl)ethane; X- = halide, thiophenolate, phenylacetylide]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (15). pp. 3167-3171. ISSN 1434-1948, 1099-0682
Full text not available from this repository. (Request a copy)Abstract
Complexes of the type Cu-I(tripod)X [tripod =1,1,1-tris(diphenylphosphanylmethyl)ethane; X- = Br-, I-, PhS-, PhC C-] are phosphorescent in solution and in the solid state (lambda(max) approximate to 465 nm). Calculations show that the emissive triplet is of mixed MLCT/LLCT character. The emission is facilitated by the rigid tetrahedral structure, which is imposed by the tripod ligand. Accordingly, a distortion towards a square-planar geometry, which should occur upon MLCT excitation, is prevented. On the other hand, in the triplet state the phenyl substituents of the phosphane ligands undergo a rotation which favours radiationless deactivation. As a result, the emission efficiency is relatively small in solution, but much higher in the solid state owing to the rigidity of the lattice. (c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | TRANSFER EXCITED-STATES; GAUSSIAN-BASIS SETS; PHOTOPHYSICAL PROPERTIES; METAL-COMPLEXES; TEMPERATURE-DEPENDENCE; COPPER(I) COMPLEXES; SOLID-STATE; ATOMS LI; EMISSION; LIGANDS; electronic spectra; luminescence; copper complexes; phosphane ligands; quantumchemical calculations |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 03 May 2021 09:42 |
| Last Modified: | 03 May 2021 09:42 |
| URI: | https://pred.uni-regensburg.de/id/eprint/35778 |
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