Spectroscopic investigation of the solvation of organic molecules in superfluid helium droplets

Lehnig, R. and Slenczka, Alkwin (2005) Spectroscopic investigation of the solvation of organic molecules in superfluid helium droplets. JOURNAL OF CHEMICAL PHYSICS, 122 (24): 244317. ISSN 0021-9606, 1089-7690

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Abstract

The spectroscopy of molecules doped into superfluid helium nanodroplets provides valuable information on the process of solvation in superfluid helium. In continuation of an earlier report on emission spectra of various phthalocyanines showing a splitting of all molecular transitions in the range of about 5-12 cm(-1), the emission spectra of tetracene, pentacene, and perylene in superfluid helium droplets are presented. The new spectra and the results obtained for the phthalocyanines are explained by an empirical model which accounts for the existence of different metastable configurations of a nonsuperfluid solvation layer around the guest molecule. (c) 2005 American Institute of Physics.

Item Type: Article
Uncontrolled Keywords: MIXED-CRYSTALS; LIQUID-HELIUM; HE DROPLETS; PENTACENE; TETRACENE; PHTHALOCYANINE; COMPLEXES; PERYLENE; EMISSION; MATRICES;
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Alkwin Slenczka
Depositing User: Dr. Gernot Deinzer
Date Deposited: 10 May 2021 08:00
Last Modified: 10 May 2021 08:00
URI: https://pred.uni-regensburg.de/id/eprint/35988

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