Enhanced photoreactivity of zirconium(IV) and hafnium(TV) porphyrin complexes promoted by water molecules

Knoer, Guenther and Strasser, Andreas (2005) Enhanced photoreactivity of zirconium(IV) and hafnium(TV) porphyrin complexes promoted by water molecules. INORGANIC CHEMISTRY COMMUNICATIONS, 8 (5). pp. 471-473. ISSN 1387-7003,

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Abstract

The visible-light-induced photoreduction of zirconium and hafnium tetraphenylporphyrin derivatives carrying axial benzoato ligands yields the corresponding two-electron-reduced porphodimethene metal complexes and requires the assistance of water as an essential cofactor for substrate conversion in degassed solution. © 2005 Elsevier B.V. All rights reserved.

Item Type: Article
Uncontrolled Keywords: ; porphyrins; zirconium; hafnium; photochemistry; electron transfer; catalysis
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors
Depositing User: Dr. Gernot Deinzer
Date Deposited: 14 May 2021 09:06
Last Modified: 14 May 2021 09:06
URI: https://pred.uni-regensburg.de/id/eprint/36176

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