Walenzyk, Thomas and Koenig, Burkhard (2005) Immobilised zinc(II) cyclen complexes as catalytic reagents for phosphodiester hydrolysis. INORGANICA CHIMICA ACTA, 358 (7). pp. 2269-2274. ISSN 0020-1693, 1873-3255
Full text not available from this repository. (Request a copy)Abstract
Many hydrolases found in nature have Zn(II) ions at their active site. Artificial hydrolases as alternatives for non-enzymatic hydrolysis were prepared by attaching Zn(II) cyclen complexes with an alcohol pendant to a polymeric support. These modified polymers showed a 10(4)-fold enhanced intrinsic reactivity for the hydrolysis of activated phosphodiesters over the non-catalysed reaction in solution. (c) 2005 Elsevier B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | CO(III) COMPLEX; DNA; POLYSTYRENE/; NUCLEASES; SITE; phosphoester hydrolysis; immobilised metal complexes; zinc (II) cyclen |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 17 May 2021 05:15 |
| Last Modified: | 17 May 2021 05:15 |
| URI: | https://pred.uni-regensburg.de/id/eprint/36253 |
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