Jezek, Eva and Schall, Andreas and Kreitmeier, Peter and Reiser, Oliver (2005) Radical cyclizations as key step for the stereoselective synthesis of Bi- and tricyclic sesquiterpene Lactones. SYNLETT (6). pp. 915-918. ISSN 0936-5214, 1437-2096
Full text not available from this repository. (Request a copy)Abstract
A strategy towards the stereoselective synthesis of bi-and tricyclic sesquiterpene lactones is reported. As key step radical cyclizations of appropriately functionalized trans-4,5-disubstituted gamma-butyrolactones, which are readily available from methyl 2-furoate, were carried out to give rise to 5,6-, 5,7- and 5,7,5-ring systems in diastereo- and enantiomerically pure form.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ENANTIOSELECTIVE SYNTHESIS; CONSTRUCTION; STRATEGY; ESTERS; RINGS; radical reactions; radicals; natural products; cyclizations; lactones |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 17 May 2021 06:42 |
| Last Modified: | 17 May 2021 06:42 |
| URI: | https://pred.uni-regensburg.de/id/eprint/36265 |
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