Suchentrunk, Christof and Daniels, J. and Somer, M. and Carrillo-Cabrera, W. and Korber, Nikolaus (2005) Synthesis and crystal structures of the polygermanide ammoniates K(4)Ge(9)(center dot)9NH(3), Rb(4)Ge(9)(center dot)5NH(3) and CS(6)Ge(18)(center dot)4NH(3). ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 60 (3). pp. 277-283. ISSN 0932-0776, 1865-7117
Full text not available from this repository. (Request a copy)Abstract
The new compounds K4Ge9 center dot 9 NH3 and Rb4Ge9 center dot 5 NH3 were prepared by the extraction of K4Ge9 and Rb4Ge9 with liquid ammonia and characterized by low temperature X-ray structure analysis. They both contain monocapped square antiprismatic Ge-9(4-) anions. Cs6Ge18 center dot 4 NH3 was prepared by the extraction of K2Cs2Ge9 with liquid ammonia in the presence of [(Bu)(3)MeN](Br2I) as an oxidizing agent, and contains a [Ge-9-Ge-9](6-) dimer in which two Ge-9(4-) anions are linked by a single Ge-Ge bond.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ZINTL ION; Zintl anion; germanide; low-temperature crystal structure analysis; liquid ammonia; solvate crystal |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Nikolaus Korber |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 28 May 2021 08:12 |
| Last Modified: | 28 May 2021 08:12 |
| URI: | https://pred.uni-regensburg.de/id/eprint/36471 |
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