Hanauer, Tobias and Kraus, Florian and Korber, Nikolaus (2005) Synthesis and crystal structure of tetraamminelithium-rubidiumtriselenide, Li(NH3)(4)RbSe3, and pentaamminesodium-rubidiumtriselenide-ammonia(1/3), Na(NH3)(5)RbSe3 center dot 3NH(3). MONATSHEFTE FUR CHEMIE, 136 (2). pp. 119-125. ISSN 0026-9247, 1434-4475
Full text not available from this repository. (Request a copy)Abstract
The ammoniates Li(NH3)(4)RbSe3 and Na(NH3)(5)RbSe3 . 3NH(3) were prepared by the reduction of Rb2Se5 with lithium or sodium in liquid ammonia. Single crystals were isolated and characterized by X-ray structure analysis using low temperature techniques. Both compounds contain triselenide anions Se-3(2-), which coordinate to rubidium cations forming (infinity)(1)[RbSe3](-) or (infinity)(1)[Rb(NH3)(2)Se-3](-) chains. The chains are separated in the crystal structures by the homoleptic ammine complexes Li(NH3)(4)(+) and Na(NH3)(5)(+).
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | CESIUM; alkali metal; ammoniate; crystal structure; liquid ammonia; selenide |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Nikolaus Korber |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 31 May 2021 06:50 |
| Last Modified: | 31 May 2021 06:50 |
| URI: | https://pred.uni-regensburg.de/id/eprint/36540 |
Actions (login required)
 |
View Item |
