Scheer, Manfred and Vogel, Ulf and Becker, Uta and Balazs, Gabor and Scheer, Petra and Hoenle, Wolfgang and Becker, Michael and Jansen, Martin (2005) Synthesis and characterisation of novel complexes containing group 15 elements and their potential use as molecular precursors for the formation of transition metal pnictides. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (1). pp. 135-141. ISSN 1434-1948, 1099-0682
Full text not available from this repository. (Request a copy)Abstract
The reaction of [{W(CO)(5)}(2)PCl] with K[Co(CO)(4)] yields the novel compounds [{W(CO)(4)CO2(CO)(6)}{mu(3)-PW(CO)(5)}(2)] (3) and [{(CO)(4)WCO3(CO)(6)}{mu(3)-PW(CO)(5)}(3)] (4) along with known derivatives [CO2(CO)(6){mu,eta(2)-PW(CO)(5)}(2)] (1) and [CO3(CO)(9){mu(3)-PW(CO)(5)}] (2). The complex [{W-2(CO)(8)(mu-CO)}{mu,eta(2):eta(1):eta(1)-PW(CO)(5)}(2))] (5) was synthesised by treating Na-2[W-2(CO)(10)] with PBr3. Reaction of K[Mn(CO)(5)] with SbCl3 affords [Sb{Mn(CO)(5)}(3)] (6) in high yields. The spectroscopic and structural characterisation of the novel products is discussed, as well as the thermolytic behaviour of 2, 3 and 6 for the potential formation of novel phases of transition metal pnictides. (C) Wiley-VCH Verlag GmbH Co.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | PHOSPHORUS TRIPLE BOND; MAIN GROUP; CLUSTERS; LIGANDS; STABILIZATION; COBALT; cobalt; cluster compounds; phosphorus; thermochemistry; tungsten |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 02 Jun 2021 06:39 |
| Last Modified: | 02 Jun 2021 06:39 |
| URI: | https://pred.uni-regensburg.de/id/eprint/36686 |
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