Kunkely, Horst and Vogler, Arnd (2005) Photolysis of aqueous europium(III) azide complexes: formation of europium(II) induced by ligand-to-metal charge transfer excitation. INORGANIC CHEMISTRY COMMUNICATIONS, 8 (1). pp. 117-118. ISSN 1387-7003, 1879-0259
Full text not available from this repository. (Request a copy)Abstract
Europium(III) azide complexes are formed when azide is added to aqueous EuCl3. A new absorption appears at lambda(max) = 324 nm. It is assigned to a (N-3(-) to Eu3+) LMCT transition. LMCT excitation leads to the formation of EU2+ with phi = 7 x 10(-4) at lambda(irr) = 333 nm. (C) 2004 Elsevier B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ELECTRON TRANSFER SPECTRA; LANTHANIDE COMPLEXES; EU3+; EU2+; PHOTOREDUCTION; REDUCTION; YIELD; electronic spectra; photochemistry; europium; azide complexes |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 02 Jun 2021 08:25 |
| Last Modified: | 02 Jun 2021 08:25 |
| URI: | https://pred.uni-regensburg.de/id/eprint/36707 |
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