Mueller, Thomas G. and Buchner, Magnus R. and Scheubeck, Thomas J. and Korber, Nikolaus and Kraus, Florian (2016) Ammine Complexes of Na-, Ag-, Mn-, and Zn-Azides. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 642 (14). pp. 796-803. ISSN 0044-2313, 1521-3749
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The synthesis of ammine metal azides is achieved through a simple route in liquid ammonia solution. Azides of silver, sodium, manganese, and zinc were obtained as ammine complexes from liquid ammonia and the solid compounds were characterized. The NH3 solutions were investigated by means of NMR spectroscopy as well. The triamminesilver(I) azide as well as the unusual tetraamminesilver(I) and pentaamminesodium(I) azides are presented. The structures of the hexaamminemanganese(II) and hexaamminezinc(II) azides, which crystallize with four ammonia molecules of solvation, are elucidated. From these compounds the binary azides Mn(N-3)(2) and Zn(N-3)(2) were obtained by (careful) heating.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | CRYSTAL-STRUCTURE DETERMINATION; PROTON-MAGNETIC-RESONANCE; CLOSED-SHELL ATTRACTION; N-15 NMR-SPECTROSCOPY; METAL AZIDES; CLICK CHEMISTRY; AMMONIA; NITRIDE; SPECTRA; SILVER; Liquid ammonia; Silver azide; Sodium azide; Manganese azide; Zinc azide |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Nikolaus Korber |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 15 Mar 2019 11:14 |
| Last Modified: | 15 Mar 2019 11:14 |
| URI: | https://pred.uni-regensburg.de/id/eprint/3673 |
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