Pfitzner, Arno and Zabel, Manfred (2005) Preparation and crystal structure of MnBiSe2I. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 631 (8). pp. 1439-1441. ISSN 0044-2313,
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Black single crystals of MnBiSe2I were obtained by the reaction of stoichiometric amounts of Mn, Bi, BiI3, and Se at 600 degrees C for 7 days. The compound crystallizes in the monoclinic system, space group C2/m, with a = 13.428(2), b = 4.112(1), c = 10.130(2) angstrom, beta = 90.97(2)*, and Z = 4. The crystal structure refinement based on 849 reflections converged at R = 0.0380 and wR2 = 0.0916, respectively. MnBiSe2I forms a layer structure consisting of MnSe6 octahedra, MnSe2I4 octahedra, and BiSe3I2 pyramids.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ; manganese; bismuth; selenium; iodine; sulfosalts; crystal structure |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Arno Pfitzner |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 21 Jun 2021 08:11 |
| Last Modified: | 21 Jun 2021 08:11 |
| URI: | https://pred.uni-regensburg.de/id/eprint/36848 |
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