Wiesler, Katharina and Korber, Nikolaus (2005) Synthesis and crystal structure of {[Li(NH3)(4)](2)[18-crown-6]}[Li(NH3)(4)](2)(Sn(3)ph(6))(2) center dot 4 NH3. ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 220 (2-3). pp. 188-191. ISSN 0044-2968,
Full text not available from this repository. (Request a copy)Abstract
{[Li(NH3)(4)](2)[18-crown-6]}[Li(NH3)412(Sn(3)ph(6))(2) (.) 4 NH3 was prepared by reacting diphenyltin dichloride with lithium and 18-crown-6 in liquid ammonia. The crystal structure was obtained from low temperature single crystal X-ray data (P2(1)/a, Z=2, a=18.483(5) angstrom, b=13.240(2) angstrom, c = 22.919(5) angstrom; beta=103.65(3)degrees). The structure is built from previously unknown catena-hexaphenyltristannandiide anions, Sn(3)ph(6)(2-), isolated tetraamminelithium complexes, and novel {[Li(NH3)(4)](2)[18-crown-6]}(2+) cations. In the latter divalent cation, two tetraamminelithium complexes coordinate to both sides of the crown ether via hydrogen bonds.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | AMMONIATE; ANION; |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Nikolaus Korber |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 21 Jun 2021 07:34 |
| Last Modified: | 21 Jun 2021 07:34 |
| URI: | https://pred.uni-regensburg.de/id/eprint/36852 |
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