(EtZn)(4)Zn-2(PSitBu(3))4 - a homometallic phosphanediide of zinc with a novel Zn6P4 cage

Westerhausen, Matthias and Sapelza, Gerhard and Zabel, Manfred and Pfitzner, Arno (2004) (EtZn)(4)Zn-2(PSitBu(3))4 - a homometallic phosphanediide of zinc with a novel Zn6P4 cage. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 59 (11-12). pp. 1548-1550. ISSN 0932-0776, 1865-7117

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Abstract

The metalation of tri(tert-butyl)silylphosphane with diethylzinc yields quantitatively the title compound tetraethyltetrakis(tri(tert-butyl)silylphosphanediido)hexazinc (1) with a novel Zn6P4 cage with two Zn2P2 rings interconnected by two zinc atoms.

Item Type: Article
Uncontrolled Keywords: = ZN; COMPLEXES; CD; ORGANOZINC; LIGANDS; SN; cage compounds; geminal dianions; metalation; phosphanediides; zinc
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Arno Pfitzner
Depositing User: Dr. Gernot Deinzer
Date Deposited: 25 Jun 2021 12:26
Last Modified: 25 Jun 2021 12:26
URI: https://pred.uni-regensburg.de/id/eprint/37057

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