Kunkely, Horst and Vogler, Arnd (2004) Optical properties of bis(cyclopentadienyl)magnesium: excimer-type luminescence of the bis(cyclopentadienyl) ligand frame. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 689 (18). pp. 2940-2943. ISSN 0022-328X, 1872-8561
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The electronic spectra of solid MgCp2 (CP = cyclopentadienyl) show features which indicate the presence of intramolecular inter-ligand interactions. The fluorescence Of MgCp2 (lambda(max) = 363 nm) undergoes a considerable Stokes shift which is apparently caused by a bonding attraction between both Cp rings in the excited state. An additional phosphorescence of the (Cp-)(2) fragment (lambda(max) = 535 nm) appears at 77 K. (C) 2004 Elsevier B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | RUTHENOCENE; SPECTRA; CYCLOPENTADIENYL; STATE; PHOTOLUMINESCENCE; SPECTROSCOPY; METALLOCENES; COMPLEXES; luminescence; metallocenes; magnesium |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 28 Jun 2021 11:53 |
| Last Modified: | 28 Jun 2021 11:53 |
| URI: | https://pred.uni-regensburg.de/id/eprint/37188 |
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