Strasser, Andreas and Vogler, Arnd (2004) Phosphorescence of gadolinium(III) chelates under ambient conditions. INORGANICA CHIMICA ACTA, 357 (8). pp. 2345-2348. ISSN 0020-1693, 1873-3255
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The gadolinium(III) chelates Gd(dtpaH(2)), Gd(hfaC)(3), Gd(tta)(3) and Gd(qu)(3) with dtpa = 1,1,4,7,7-diethylenetriaminepentaacetate, hfac = hexafluoroacetylacetonate, tta = thenoyltrifluoroacetonate and qu 8-quinolinolate (or oxinate) show a phosphorescence under ambient conditions. While the UV emission of Gd(dtpaH(2)) at lambda(max) = 312 nm comes from a metal-centered ff state, the bluish (lambda(max) = 462 nm), green (lambda(max) = 505 nm) and red (lambda(max) = 650 nm) luminescence of Gd(hfaC)(3), Gd(tta)(3) and Gd(qu)(3), respectively, originates from the lowest-energy intraligand triplets. (C) 2004 Elsevier B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | METAL-COMPLEXES; LUMINESCENCE; ABSORPTION; SPECTRA; gadolinium; compounds; phosphorescence |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 13 Jul 2021 11:24 |
| Last Modified: | 13 Jul 2021 11:24 |
| URI: | https://pred.uni-regensburg.de/id/eprint/37542 |
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