Kunkely, Horst and Vogler, Arnd (2004) Photolysis of the ion pair [Pt-IV(NH3)(5) Cl]3+S2O82-: reduction of platinum(IV) induced by outer-sphere charge transfer excitation. INORGANICA CHIMICA ACTA, 357 (8). pp. 2401-2403. ISSN 0020-1693, 1873-3255
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The ion pair [Pt-IV(NH3)(5)Cl]3+S2O82- shows a S2O82- --> [Pt(NH3)(5)Cl](3+) outer-sphere charge transfer (OSCT) absorption at lambda(max) = 267 nm. OSCT excitation leads to the reduction of Pt(IV) by S2O82- to Pt(II) with phi = 3 x 10(-3) at lambda(irr) = 280 nm. (C) 2004 Elsevier B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | COMPLEXES; DIOXYGEN; CHLOROPENTAAMMINEPLATINUM(IV); METAL; electronic spectra; charge transfer; photochemistry; platinum; peroxide |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 13 Jul 2021 11:25 |
| Last Modified: | 13 Jul 2021 11:25 |
| URI: | https://pred.uni-regensburg.de/id/eprint/37543 |
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