Seitz, Michael and Kaiser, Anja and Powell, Douglas R. and Borovik, Andrew S. and Reiser, Oliver (2004) Predetermined helical chirality in octahedral complexes with a novel pentadentate C-2-symmetrical chiral bis(oxazoline) ligand. ADVANCED SYNTHESIS & CATALYSIS, 346 (7). pp. 737-741. ISSN 1615-4150, 1615-4169
Full text not available from this repository. (Request a copy)Abstract
The first example of the pentadentate bis(oxazolines) has been synthesized using a modular approach that readily provides access to this ligand class. This ligand allows the controlled transfer of carbon-centered to octahedral, metal-centered chirality, as demonstrated both in the solid state as well as in solution. The characteristic CD band has been identified for dicationic, octahedral transition metal complexes with the Delta(2)-configuration.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ASYMMETRIC CATALYSIS; METAL-COMPLEXES; STEREOSELECTIVITY; CYCLOPROPANATION; HYDROSILYLATION; 1,4-ADDITION; VERSATILE; CHEMISTRY; KETONES; BINDING; chirality; circular dichroism; helical structures; structure elucidation; transition metals |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 13 Jul 2021 11:48 |
| Last Modified: | 13 Jul 2021 11:48 |
| URI: | https://pred.uni-regensburg.de/id/eprint/37548 |
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