Kunkely, Horst and Vogler, Arnd (2004) Excited state properties of diphenylmercury: photolysis and luminescence under ambient conditions. INORGANIC CHEMISTRY COMMUNICATIONS, 7 (6). pp. 741-743. ISSN 1387-7003, 1879-0259
Full text not available from this repository. (Request a copy)Abstract
In solution (HgPh2)-Ph-II undergoes a photoredox decomposition (phi = 0.006 at lambda(irr) = 254 nm in CH3CN) which is induced by ligand-to-metal charge transfer excitation. In the solid state this decomposition is largely prevented but a phosphorescence appears which originates from the lowest-energy pipi* (phenyl) intraligand triplet. (C) 2004 Elsevier B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ABSORPTION SPECTRA; MERCURY; PHOTOLUMINESCENCE; CYCLOHEXANE; GENERATION; COMPLEXES; BIPHENYL; electronic spectra; photoluminescence; photochemistry; charge transfer; mercury |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 19 Jul 2021 13:21 |
| Last Modified: | 19 Jul 2021 13:21 |
| URI: | https://pred.uni-regensburg.de/id/eprint/37583 |
Actions (login required)
 |
View Item |
