Quantum solvation of phthalocyanine in superfluid helium droplets

Lehnig, R. and Slenczka, Alkwin (2004) Quantum solvation of phthalocyanine in superfluid helium droplets. JOURNAL OF CHEMICAL PHYSICS, 120 (11). pp. 5064-5066. ISSN 0021-9606, 1089-7690

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Abstract

We have measured quantum states of the solvent-solute system of phthalocyanine in superfluid helium droplets in a high resolution pump-probe experiment. This provides evidence for the attribution of a splitting effect in the emission spectra of phthalocyanine in helium droplets to the relaxation of the first helium layer upon electronic excitation, measured recently by us. Our experimental results are a strong indication for the first helium layer playing a key roll for the solvation of molecules in helium droplets and, thus, for their spectroscopic features. (C) 2004 American Institute of Physics.

Item Type: Article
Uncontrolled Keywords: CARBONYL SULFIDE; SPECTRA; ATOMS; CLUSTERS; LINE;
Subjects: 500 Science > 530 Physics
500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Alkwin Slenczka
Depositing User: Dr. Gernot Deinzer
Date Deposited: 21 Jul 2021 10:34
Last Modified: 21 Jul 2021 10:34
URI: https://pred.uni-regensburg.de/id/eprint/37875

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