Self-diffusion of molecules in aqueous solutions of tetramethylurea

Rodnikova, M. N. and Samigullin, F. M. and Bartels, I. and Kayumova, D. B. (2004) Self-diffusion of molecules in aqueous solutions of tetramethylurea. RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY, 78 (2). pp. 303-304. ISSN 0036-0244

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Abstract

Solutions of tetramethylurea (I) in light and heavy water were studied by the proton spin echo method over a wide concentration range at different temperatures. The energies of self-diffusion activation for species in these systems were calculated. In the both systems, the lowest coefficient of self-diffusion and the highest energy of activation for all the temperatures studied (288 to 313 K) were found for its similar to20 mol % solution. which corresponds to a congruently melting compound in the solid phase and to maximum sound viscosity, density, and speed in aqueous solutions of tetramethylurea. The low-concentration range of compound I (from 1.2 to 5 mol %) proved to be featureless.

Item Type: Article
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie
Depositing User: Dr. Gernot Deinzer
Date Deposited: 22 Jul 2021 11:33
Last Modified: 22 Jul 2021 11:33
URI: https://pred.uni-regensburg.de/id/eprint/38059

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