Optical properties of ethylenebis(indenyl)zirconium(IV) binolate with binol=1, 1 '-binaphthyl-2,2 '-diol. Binolate intraligand phosphorescence under ambient conditions

Kunkely, Horst and Vogler, Arnd (2004) Optical properties of ethylenebis(indenyl)zirconium(IV) binolate with binol=1, 1 '-binaphthyl-2,2 '-diol. Binolate intraligand phosphorescence under ambient conditions. INORGANIC CHEMISTRY COMMUNICATIONS, 7 (1). pp. 35-37. ISSN 1387-7003, 1879-0259

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Abstract

The complex ethylenebis(indenyl)zirconium(IV) binolate with binol = 1, 1'-binaphthyl-2,2'-diol is characterized by a lowest-energy pipi* binolate IL (intraligand) excited state (absorption lambda(max) = 348 nm). The IL triplet undergoes an emission at lambda(max) = 490 nm under ambient conditions. (C) 2003 Elsevier B.V. All rights reserved.

Item Type: Article
Uncontrolled Keywords: ZIRCONIUM THIOLATE COMPLEXES; CHARGE-TRANSFER; CRYSTAL-STRUCTURES; EMISSION; PHOTOLUMINESCENCE; DERIVATIVES; STATES; electronic spectra; luminescence; charge transfer; zirconium complexes; phenolate complexes
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler
Depositing User: Dr. Gernot Deinzer
Date Deposited: 23 Jul 2021 09:24
Last Modified: 23 Jul 2021 09:24
URI: https://pred.uni-regensburg.de/id/eprint/38175

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