Tight-binding description of the STM image of molecular chains

Calev, Yoel and Cohen, Hezy and Cuniberti, Gianaurelio and Nitzan, Abraham and Porath, Danny (2004) Tight-binding description of the STM image of molecular chains. ISRAEL JOURNAL OF CHEMISTRY, 44 (1-3). pp. 133-143. ISSN 0021-2148, 1869-5868

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Abstract

A tight-binding model for scanning tunneling microscopy images of a molecule adsorbed on a metal surface is described. The model is similar in spirit to that used to analyze conduction along molecular wires connecting two metal leads and makes it possible to relate these two measurements to each other. In particular, the dependence of molecular conduction properties along and across a molecular chain on the chain length, intersite electronic coupling strength, and on thermal and disorder effects are discussed and contrasted. It is noted that structural or chemical defects that may affect drastically the conduction along a molecular chain have a relatively modest influence on conduction across the molecular wire in the transverse direction.

Item Type: Article
Uncontrolled Keywords: DNA; TRANSPORT; CONDUCTION; JUNCTIONS; SYSTEMS;
Subjects: 500 Science > 530 Physics
500 Science > 540 Chemistry & allied sciences
Divisions: Physics > Institute of Theroretical Physics > Alumni or Retired Professors > Group Gianaurelio Cuniberti
Depositing User: Dr. Gernot Deinzer
Date Deposited: 23 Jul 2021 09:33
Last Modified: 23 Jul 2021 09:33
URI: https://pred.uni-regensburg.de/id/eprint/38180

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