Tandon, V. K. and Chhor, R. B. (2004) Metal mediated dechlorination - A new route to nitriles. LETTERS IN ORGANIC CHEMISTRY, 1 (1). pp. 40-42. ISSN 1570-1786
Full text not available from this repository. (Request a copy)Abstract
1,4-Dichloro-1,4-disubstituted-2,3-diaza-1,3-butadiene 1 undergo cyclodechlorination in presence of Be metal to form cyclazines 3a. Reaction of 1 with Cu, Zn and Mn metals results in formation of nitriles 2. Cyclazines 3 on further oxidation with H2O2 in CH3COOH form NO donors, 1,2-dioxides 4.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ONE-POT SYNTHESIS; VASODILATORY PROPERTIES; OXIDE; ALDEHYDES; cyclodechlorination; chlorination; nitriles; cyclazines; NO donors |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 23 Jul 2021 10:35 |
| Last Modified: | 23 Jul 2021 10:35 |
| URI: | https://pred.uni-regensburg.de/id/eprint/38205 |
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