Vogler, Arnd (2016) Photoluminescence and photochemistry of Pt(II)(PPh3)(2)(C6O6) induced by rhodizonate IL excitation. INORGANIC CHEMISTRY COMMUNICATIONS, 74. pp. 90-92. ISSN 1387-7003, 1879-0259
Full text not available from this repository.Abstract
The complex Pt(II)(PPh3)(2)(C6O6) was prepared by the reaction of Ag2C6O6 with cis-Pt(PPh3)(2)Cl-2 in acetonitrile. Pt(PPh3)(2)(C6O6) is characterized by a lowest-energy IL (rhodizonate) excited state. The complex shows an IL fluorescence, but is also photoactive. The photolysis leads to the conversion of rhodizonate to croconate in the coordinated state: Pt(II)(PPh3)(2)(C6O6) -> Pt(II)(PPh3)(2)(C5O3) + CO. (C) 2016 Elsevier B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | METAL-COMPLEXES; CROCONATE ION; OXOCARBONS; DIANION; Platinum(II); Rhodizonate; Photoluminescence; Photochemistry |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 10 Apr 2019 07:23 |
| Last Modified: | 10 Apr 2019 07:23 |
| URI: | https://pred.uni-regensburg.de/id/eprint/3850 |
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