Kozhevnikov, V. N. and Kozhevnikov, D. N. and Rusinov, V. L. and Chupakhin, O. N. and Koenig, Burkhard (2003) Synthesis of functionalized fluorescent europium(III) terpyridyl chelates. SYNTHESIS-STUTTGART (15). pp. 2400-2404. ISSN 0039-7881, 1437-210X
Full text not available from this repository. (Request a copy)Abstract
The synthesis of substituted terpyridines via triazine intermediates is described. The intermediates allow the facile introduction of cyano groups, which are converted into amino diacetic acid moieties. Together with the terpyridine nitrogen atoms they shield coordinated europium(III) ions completely from the solvent. The terpyridines may be further functionalized for specific applications using ligands, bromo substituents, and standard transition metal mediated coupling methods. This makes the title compounds valuable intermediates for the preparation of luminescent probes in biochemistry, medicinal diagnostics or materials science.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | TIME-RESOLVED FLUORESCENCE; VERSATILE STRATEGY; LUMINESCENCE; TERBIUM(III); COMPLEXES; BINDING; SYSTEMS; ASSAYS; METAL; heterocycles; pyridines; diels-alder reaction; ligands; lanthanide |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 27 Jul 2021 13:10 |
| Last Modified: | 27 Jul 2021 13:10 |
| URI: | https://pred.uni-regensburg.de/id/eprint/38503 |
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