Suchentrunk, Christof and Korber, Nikolaus (2003) Reduction of isoquinoline and indole with cesium in liquid ammonia. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 58 (10). pp. 990-996. ISSN 0932-0776
Full text not available from this repository.Abstract
Isoquinoline and indole were reduced with solutions of cesium in liquid ammonia and the resulting crystalline compounds isolated as ammonia-rich solvate crystals. The reduction of isoquinoline yields the anion bisisoquinoline-2,2'-diide in the compound Cs2C18H14N2 . (7/2) NH3 as the result of a coupling reaction. Indole is reduced to the 5,8-dihydroindolide anion in the ammoniate CsC8H8N . 3NH(3). Both anions display interactions between their aromatic pi-systems and the cesium cations.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | liquid ammonia; isoquinoline; indole; cesium; low-temperature crystal structure determination |
| Subjects: | 500 Science > 540 Chemistry & allied sciences |
| Divisions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Nikolaus Korber |
| Depositing User: | Dr. Gernot Deinzer |
| Date Deposited: | 29 Jul 2021 09:39 |
| Last Modified: | 29 Jul 2021 09:39 |
| URI: | https://pred.uni-regensburg.de/id/eprint/38591 |
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