Fluorescence studies on fluid ordered membranes using lipophilic ruthenium-ligand complexes with long luminescence decay times

Augustin, Christine M. and Wolfbeis, Otto S. (2003) Fluorescence studies on fluid ordered membranes using lipophilic ruthenium-ligand complexes with long luminescence decay times. JOURNAL OF MOLECULAR LIQUIDS, 107 (1-3). pp. 141-154. ISSN 0167-7322

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Abstract

The fluidity of lipid membranes contained in aqueous medium was studied using new fluorescent lipophilic ruthenium-ligand complexes containing dipalmitoyl-glycerophospho-ethanolamine (PE) or hexadecyl side groups, respectively. The new probes display long luminescence decay times and polarized emission, thus making them viable molecular sensors for studying the dynamics and molecular orientation of ordered liquids. Experiments are reported in which the probes were incorporated into lipid bilayers of vesicles, and their luminescence was studied with respect to temperature-dependent emission intensity, decay time and steady-state luminescence polarization. (C) 2003 Elsevier B.V. All rights reserved.

Item Type: Article
Uncontrolled Keywords: NUCLEAR-MAGNETIC-RESONANCE; CHOLESTEROL; IMMUNOASSAYS; EQUILIBRIA; ANISOTROPY; LOCATION; MIXTURES; PROTEIN; PROBES; OXYGEN; lipid membrane probe; ruthenium-ligand complex; luminescence; decay time; light polarization
Subjects: 500 Science > 540 Chemistry & allied sciences
Divisions: Chemistry and Pharmacy > Institut für Analytische Chemie, Chemo- und Biosensorik
Depositing User: Dr. Gernot Deinzer
Date Deposited: 29 Jul 2021 11:02
Last Modified: 29 Jul 2021 11:02
URI: https://pred.uni-regensburg.de/id/eprint/38669

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